Abstract:
This dataset contains geochemistry measurements and fossil diatom counts made on a sediment core from La Grange Cop lake, Marion Island (46deg94S, 37deg60E, 60 m above sea level). The dataset consists of diatom relative frequencies, diatom principal components analysis (PCA), and diatom-inferred conductivity, ITRAX scanning XRF elemental percentages and XRF PCA, C%, N%, and delta13C measurements, and magnetic susceptibility measurements. Ages of the sediment samples were assigned based on an age depth model derived from 210Pb, 137Cs, and 14C measurements and span the last c. 700 years.
This project was funded by UK Natural Environment Research Council Grant NE/K004514/1 to Dominic A Hodgson and a Research Foundation-Flanders travel bursary to Elie Verleyen.
Keywords:
Diatoms, ITRAX, Marion Island, geochemistry, magnetic susceptibility, paleolimnology, subantarctic islands
Perren, B., Hodgson, D., Roberts, S., Sime, L., Van Nieuwenhuyze, W., Verleyen, E., & Vyverman, W. (2020). Fossil diatom and geochemistry data from a 700-year core from La Grange Cop, subantarctic Marion Island. (Version 1.0) [Data set]. UK Polar Data Centre, Natural Environment Research Council, UK Research & Innovation. https://doi.org/10.5285/49a1ec0e-ae5f-4df5-a59b-fa6dff614678
| Use Constraints: | This data is covered by a UK Open Government Licence (http://www.nationalarchives.gov.uk/doc/open-government-licence/version/3/) Please cite this dataset as follows: Perren, B., Hodgson, D., Roberts, S., Sime, L., Van Nieuwenhuyze, W., Verleyen, E., & Vyverman, W. (2020). Fossil diatom and geochemistry data from a 700-year core from La Grange Cop, subantarctic Marion Island. (Version 1.0) [Data set]. UK Polar Data Centre, Natural Environment Research Council, UK Research & Innovation. https://doi.org/10.5285/49A1EC0E-AE5F-4DF5-A59B-FA6DFF614678 |
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| Creation Date: | 2020-07-14 |
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| Dataset Progress: | Complete |
| Dataset Language: | English |
| ISO Topic Categories: |
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| Parameters: |
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| Personnel: | |
| Name | PDC BAS |
| Role(s) | Metadata Author |
| Organisation | British Antarctic Survey |
| Name | Dr Bianca Perren |
| Role(s) | Investigator |
| Organisation | British Antarctic Survey |
| Name | Dr Dominic Hodgson |
| Role(s) | Investigator |
| Organisation | British Antarctic Survey |
| Name | Dr Stephen J Roberts |
| Role(s) | Investigator |
| Organisation | British Antarctic Survey |
| Name | Dr Louise Sime |
| Role(s) | Investigator |
| Organisation | British Antarctic Survey |
| Name | Dr Wim Van Nieuwenhuyze |
| Role(s) | Investigator |
| Organisation | Ghent University |
| Name | Dr Elie Verleyen |
| Role(s) | Investigator |
| Organisation | Ghent University |
| Name | Dr Wim Vyverman |
| Role(s) | Investigator |
| Organisation | Ghent University |
| Parent Dataset: | N/A |
| Reference: | Main reference: Perren et al. (in review) Processing references: Blaauw, M., & Christen, J. A. (2011). Flexible paleoclimate age-depth models using an autoregressive gamma process. Bayesian analysis, 6(3), 457-474. Davies, S. J. L., H.F., Roberts, S.J. (2015), Micro-XRF Core Scanning in Palaeolimnology: Recent Developments, In G. Rothwell, & I. Croudace (Eds.), Micro-XRF studies of sediment cores: A non-destructive tool for the environmental sciences, pp. 373-390. Dordrecht: Springer. doi:10.1007/978-94-017-9849-5 Gunn, D. E., & Best, A. I. (1998). A new automated nondestructive system for high resolution multi-sensor core logging of open sediment cores. Geo-Marine Letters, 18(1), 70-77. Kylander, M. E., L. Ampel, B. Wohlfarth, and D. Veres (2011), High-resolution X-ray fluorescence core scanning analysis of Les Echets (France) sedimentary sequence: new insights from chemical proxies, J Quaternary Sci, 26(1), 109-117. Renberg, I. (1990). A procedure for preparing large sets of diatom slides from sediment cores. Journal of Paleolimnology, 4(1), 87-90. Van de Vijver, B., Y. Frenot, and L. Beyens (2002), Freshwater diatoms from Ile de la Possession (Crozet Archipelago, Subantarctica), 412 pages pp., Cramer in der Gebrüder Borntraeger Verlagsbuchhandlung, Berlin. |
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| Lineage: | Cores were extracted from the deepest part (~4m depth) of La Grange Cop, on Marion Island (46deg56'S, 37deg35'E) using a Livingston piston core in 2013. The uppermost sediments were retrieved using a UWITEC corer, which was extruded and subsampled at 0.5 cm intervals in the field. Age determinations were made using 14C, 210Pb and 137Cs radiometric methods on bulk organic sediments. Age-depth models were generated using the software package BACON in R (Blaauw and Christen, 2011). Diatoms were isolated from the sediments using standard oxidative techniques (Renberg, 1990) and mounted on plain glass coverslips using NAPHRAX mounting medium. Taxonomic assignments were made using reference literature primarily with Van de Vijver et al. (2002) and using reference photographs to ensure consistency with the diatom-conductivity model and amongst subantarctic island analysts. At least 400 valves were identified from each slide on an Olympus BX60 microscope at 1000x magnification and phase contrast under oil immersion. PCA was performed on centered relative percentage diatom data (>1% in any one sample) from the lake using the software package C2 (Juggins, 2016). Changes in bulk sediment geochemistry was undertaken on flat half-core wet sediment surfaces using an ITRAX core scanner at Aberystwyth University fitted with a Molybdenum (Mo) X-ray tube. X-radiography settings were 50 kV, 50mA, 200ms; micro-XRF; Mo settings: 30 kV, 50 mA, count time 10 seconds, 200 micro-m or 2 mm interval with 50- or 5-point moving average for 1 cm subsample interval equivalence. Machine and sample calibration was undertaken using a synthetic glass standard and XRF fused glass discs from the core at the start and end of each core-site run. Raw count per second (cps) data were analysed using the Q-spec spectra matching software (Cox Analytical). Data are presented as percentages of the total scatter-normalised sum, following established total-scatter normalisation procedures (Kylander et al., 2011; Davies et al., 2015), rather than equivalent whole-rock percentages. The uppermost sediments were flocculent and could not be preserved intact for scanning. Magnetic susceptibility (MS) (Bartington Instruments MS2G 1 cm loop sensor, 10 s) was measured with a GEOTEK core logger using standard calibration procedures (Gunn and Best, 1998). Sediments were placed in 5% HCl to remove any CaCO3, then washed over Whatman 41 filter papers with deionised water and dried at 40degC in a drying cabinet. Carbon isotope ratios (delta13C), percentage total organic carbon (%TOC) and percentage total nitrogen (%TN were analysed during combustion in a Carlo Erba 1500 on<line to a VG Triple Trap and dual inlet mass spectrometer. delta13C values were converted to the VPDB scale using a within-run laboratory standard calibrated against NBS-19 and NBS-22, with C&N calibrated against an Acetanilide standard. Replicate analysis of sample material indicated a precision of ±0.1per mille for delta13C and ±0.1 for C&N. Detailed methodology can be found in Perren et al. (in review) Details on acronyms used in the ITRAX xrf data: o Kcps: (Kilo) counts per second o MSE: Mean Square Error o TSN:Total Scatter Normalized o Mo=Mo-tube µ-XRF data o inc.=incoherent scatter o coh.=coherent scatter o inc.+coh.=total scatter o El= element o PC: Principal Component |
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| Temporal Coverage: | |
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| Start Date | 2013-04-01 |
| End Date | 2013-04-30 |
| Paleo Temporal Coverage: | |
| Paleo Start Date | 1300 |
| Paleo End Date | 2012 |
| Chronostratigraphic Unit | N/A |
| Spatial Coverage: | |
| Latitude | |
| Southernmost | -46.93 |
| Northernmost | -46.93 |
| Longitude | |
| Westernmost | 37.58 |
| Easternmost | 37.58 |
| Altitude | |
| Min Altitude | N/A |
| Max Altitude | N/A |
| Depth | |
| Min Depth | N/A |
| Max Depth | N/A |
| Location: | |
| Location | Southern Africa |
| Detailed Location | Marion Island |
| Distribution: | |
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| Distribution Media | Online Internet (HTTP) |
| Distribution Size | 180 kB |
| Distribution Format | ASCII |
| Fees | N/A |
| Data Storage: | This dataset constains 4 csv files: - Marion_Diatoms.csv ~23 kB contains fossil diatom data. - Marion_geochemistry.csv ~2kb contains geochemistry data. - Marion_ITRAX_xrf.csv ~153 kB contains ITRAX xrf data - Marion_magnetic_susceptibility.csv ~2kB contains magnetic susceptibility data |